The Peroxide-induced Polymerization of Epoxides
نویسندگان
چکیده
منابع مشابه
Regio-controlled ring-opening polymerization of perfluoroalkyl-substituted epoxides.
Highly fluorinated epoxides were polymerized under mild conditions regioregularly, which gave easy access to isotactic polymers by using optically pure epoxides.
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Polymerizations of racemic mixtures of epoxides or episulfides may lead to stereoregular polymers through a stereoselective process, and to optically active polymers through a stereoelective process that gives either atactic or isotactic polymers. Monomers that have been most studied are propylene oxide, propylene sulfide and t-butyl thiirane, and their polymerization with insoluble initiators ...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1964
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.37.570